Brown probably has a stop leak additive in it or is just old.
Might have what looks like sediment floating too.
Give a flush with clean water (don't use any flush chemicals incase you disturb a leak) and refill with new, should be changed about every 3yr but rarely is on a motor unfortunately.
Plug on side of radiator that just twists if I remember right, gentle if pulling a pipe as tear easy and fit s new clip